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TRIBUTYL PHOSPHATE-HYDROCARBON DILUENT REPURIFICATION IN RADIOCHEMICAL PROCESSING AT ORNL: STATUS SUMMARY
Author(s) -
W. Davis
Publication year - 1960
Language(s) - English
Resource type - Reports
DOI - 10.2172/4187388
Subject(s) - tributyl phosphate , purex , diluent , chemistry , pilot plant , radiochemistry , hydrocarbon , waste management , phosphate , environmental science , nuclear chemistry , chromatography , extraction (chemistry) , engineering , solvent extraction , organic chemistry
The need for, and the adequacy of, the sodium carbonate washing technique in chemical purification of tributyl phosphate-hydrocarbon extractant prior to its re-use in radiochemical processing was examined, primarily in terms of Ru, Zr, and Nb activities. Operating experience from ORNL Purex and Thorex Pilot Plants is compared with Hanford operations and upper limits for activities are suggested. Recommendations are made for development studies with the ORNL Power Reactor Fuel Processing Pilot Plant. (W.D.M.

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