Open AccessREDUCTION OF CUPRIC OXIDE BY HYDROGEN. II. CONVERSION OF HYDROGEN TO WATER OVER FIXED BEDS
Author(s) -
W.D. Bond,
William E. Clark
Publication year - 1960
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/4169448
Subject(s) - argon , hydrogen , residence time (fluid dynamics) , chemistry , analytical chemistry (journal) , mass transfer , volumetric flow rate , oxide , materials science , thermodynamics , chromatography , physics , organic chemistry , geotechnical engineering , engineering
The conditions under which hydrogen could be quantitatively recovered from mixtures of gases by oxidation over fixed beds of CuO were investigated. The conversion of H/sub 2/ to H/sub 2/O by reduction of CuO in fixed beds increased with in- creasing bed length, temperature, hydrogen/argon ratio, and decreasing mesh size of CuO. Residence times required for 99% conversion in a 1- in.-diam. bed were 0.6 and 1.2 sec for 30% hydrogen-70% argon and 10% hydrogen90% argon mixtures, respectively, at a total gas flow of 1 l/min. The CuO used was 25-mil-diam. wires with a surface area of 0.019 m/sup 2//g. The residence time required for a given value of conversion decreased about 10% when the total flow rate was increased from 1 to 1.7 liters/min, which indicates that the reduction is mass-transfer controlled to a slight extent under the experimental conditions used. (auth
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