THE TRANSFORMATION TEMPERATURES OF HIGH-PURITY URANIUM. Work completed: December 31, 1957. Final Report--Metallurgy Program 3.1.1.
Author(s) -
B. Blumenthal,
J. Baumrucker,
L.T. Lloyd
Publication year - 1960
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/4160876
Subject(s) - superheating , thermodynamics , thermocouple , supercooling , uranium , materials science , cooling curve , work (physics) , melting point , thermal , thermodynamic equilibrium , metallurgy , physics , composite material
The transformation temperatures of high-purity uranium were determined by thermal analysis and dilatometry. Thermal analysis methods used include one in which the rates of heating and cooling were controlled by a differential thermocouple, and another in which repeated thermal analyses were made at independently controlled rates. The solid-state transformation temperatures and the logarithm of the heating or cooling rates at relatively low rates are related linearly. The extrapolated functions intersect at a point where the disturbing effects of hysteresis, superheating and undercooling disappear, i.e., at the equilibrium temperature. The mean transformation temperatures are 667 deg C for alpha in equilibrium beta and 775 deg C for beta in equilibrium gamma . The mean temperature for melting and freezing is 1132 deg C. (auth
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