HIGH-PRECISION DETERMINATIONS BY MEANS OF HIGH-ABSORBANCY SPECTRO- PHOTOMETRIC METHOD. APPLICATION TO THE DETERMINATION OF COBALT IN ALUMINUM
Author(s) -
Oscar Menis
Publication year - 1959
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/4118257
Subject(s) - cobalt , analytical chemistry (journal) , chemistry , accuracy and precision , spectrophotometry , coefficient of variation , aluminium , chromatography , mathematics , inorganic chemistry , statistics , organic chemistry
High-absorbancy spectrophotometry was applied to the precise determination of about 0.15% cobalt in aluminum by the 1-(2-pyridylazo)-2- naphthol method. The absorbancies of sample aliquots were measured versus a standard containing 50 mu g of cobalt. The relative concentration error for a single measurement, assuming a 1% transmittancy error, is 0.93% and the coefficient of variation of 5 cobalt determinations is 0.5%. (auth
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