HYDROGEN BONDING IN $beta$-NITRO ALCOHOLS. III. PYRIDINE COMPLEXES | Zendy

Herbert E. Ungnade | Zendy; E.D. Loughran | Zendy; L. W. Kissinger | Zendy

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HYDROGEN BONDING IN $beta$-NITRO ALCOHOLS. III. PYRIDINE COMPLEXES

Author(s) -

Herbert E. Ungnade,

E.D. Loughran,

L. W. Kissinger

Publication year - 1963

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/4026632

Subject(s) - pyridine , chemistry , dichloromethane , nitro , dissociation (chemistry) , carbon tetrachloride , hydrogen bond , hydrogen , dissociation constant , inorganic chemistry , medicinal chemistry , organic chemistry , molecule , solvent , alkyl , biochemistry , receptor

BETA -Nitro alcohols form stable 1:1 complexes with pyridine, examples of which were prepared. In solvents such as dichloromethane and carbon tetrachloride the complexes partially dissociate into their components. The dissociation constants for the equilibria were determined by infrared methods and may be used as a measure of the strength of the complex hydrogen bond. The dissociation constants decrease with increasing number of BETA -nitro groups. Some reactions of the pyridine complexes are described. (auth

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