Sealing 304L to lithia-alumina-silica (LAS) glass-ceramics
Author(s) -
W. E. Moddeman,
R. E. Pence,
Roger Massey,
R. T. Cassidy,
Daniel P. Kramer
Publication year - 1989
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/274153
Subject(s) - materials science , ceramic , thermal expansion , inconel , metallurgy , crystallization , alloy , glass ceramic , composite material , metallography , microstructure , chemistry , organic chemistry
The formation of a crack-free between 300 series stainless steel and a glass-ceramic is difficult owing to the high coefficients of thermal expansion of the stainless steels. Lithia-alumina-silica (LAS) glass-ceramics were successfully developed and sealed to 304L stainless steel. These crack-free seals were fabricated by two techniques: by adjusting the parent glass composition (reducing the Al{sub 2}O{sub 3} content), or by adjusting the sealing/crystallization cycle. All seals were hermetic, with leak rates < 10{sup -8} cc/sec STP helium. CTE and alloy yield strengths are given which show the feasibility of using these materials to make feedthroughs, pyrotechnic components, etc. Metallography, SEM, and wavelength dispersive spectroscopy show the quality and integrity of the glass-ceramic/stainless steel interface. These data are compared to those on the Inconel 718/LAS-glass seal system
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