Reaction mechanism studies of unsaturated molecules using photofragment translational spectroscopy | Zendy

Cheryl A. Longfellow | Zendy

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Reaction mechanism studies of unsaturated molecules using photofragment translational spectroscopy

Author(s) -

Cheryl A. Longfellow

Publication year - 1996

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/266645

Subject(s) - infrared multiphoton dissociation , dissociation (chemistry) , chemistry , photochemistry , spectroscopy , infrared , photodissociation , molecule , ultraviolet , infrared spectroscopy , materials science , physics , organic chemistry , optoelectronics , optics , quantum mechanics

A number of molecules have been studied using the technique of photofragment translational spectroscopy. In Chapter One a brief introduction to the experimental technique is given. In Chapter Two the infrared multiphoton dissociation (IRMPD) of acetic acid is discussed. Carbon dioxide and methane were observed for the first time as products from dissociation under collisionless conditions. Chapter Three relates an IRMPD experiment of hexafluoropropene. The predominant channel produces CFCF{sub 3} or C{sub 2}F{sub 4} and CF{sub 2}, with the heavier species undergoing further dissociation to two CF{sub 2} fragments. In Chapter Four the ultraviolet (UV) dissociation of hexafluoropropene is investigated. Chapter Five explores the IRMPD of octafluoro-1-butene and octafluoro-2-butene

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