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Effect of tetralin on the degradation of polymer in solution
Author(s) -
Giridhar Madras,
J.M. Smith,
B. J. McCoy
Publication year - 1995
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/207369
Subject(s) - tetralin , polymer , degradation (telecommunications) , solvent , polymer degradation , chemistry , kinetics , styrene , hydrogen , materials science , chemical engineering , thermodynamics , organic chemistry , copolymer , telecommunications , physics , quantum mechanics , computer science , engineering
The effect of a hydrogen-donor solvent tetralin on thermal degradation of poly(styrene-allyl alcohol) in liquid solution was investigated in a steady-state tubular flow reactor at 1000 psig at various tetralin concentrations, polymer concentrations, and temperatures. The experimental data were interpreted with continuous- mixture kinetics, and rate coefficients determined for the specific and random degradation processes

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