Open AccessSimultaneous SO{sub 2}/NO{sub x} abatement using zeolite-supported copper. Quarterly progress report, January 1, 1995--March 31, 1995
Author(s) -
Mark B. Mitchell,
Mark G. White
Publication year - 1995
Language(s) - English
Resource type - Reports
DOI - 10.2172/162172
Subject(s) - sulfate , copper , adsorption , inorganic chemistry , sulfur , zeolite , sorbent , oxide , aluminium , metal , sodium sulfate , chemistry , infrared spectroscopy , decomposition , materials science , catalysis , sodium , organic chemistry
We have significantly improved on our earlier results with a copper-impregnated alumina, obtaining reproducible results for the impregnation procedure and linear behavior with solution concentration of the precursor. The copper acetylacetonate precursor is adsorbed molecularly onto the alumina surface, with no noticeable decomposition. The adsorbed complex appears to form layers on the alumina surface, similar to results found using the same complex with a silica substrate. The materials start out as light blue powders, and after oxidation are light green. Using infrared spectroscopy, we have examined the in situ adsorption and oxidation of SO{sub 2} on the oxidized sorbent, which is dispersed copper oxide supported on aluminum oxide, and have observed that the initial species formed correspond to aluminum sulfate and aluminum sulfate. The sulfate is formed at temperatures much lower than similar experiments studying SO{sub 2} adsorption on alumina and sodium-doped alumina. As a result of oxidation, the adsorbed sulfur species, which begin as aluminum sulfate and sulfate, are converted to copper sulfate