X-Ray Raman Spectroscopy of High-Pressure Phases and Novel Materials derived from Low-Z Compounds
Author(s) -
W.J. Evans,
Peter J. Eng,
Brian Maddox,
M. Newville,
Brandon Baer,
Hyunchae Cynn,
M. J. Lipp,
Valentin Iota-Herbei,
Choong-Shik Yoo
Publication year - 2004
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/15014346
Subject(s) - raman spectroscopy , spectroscopy , plasma , full width at half maximum , materials science , laser , x ray spectroscopy , wavelength , analytical chemistry (journal) , optics , chemistry , physics , optoelectronics , nuclear physics , astronomy , chromatography
1High Pressure Physics Group, H-Division, Physics & Advanced Technologies, Lawrence Livermore National Laboratory, Livermore, CA U.S.A.; 2GSECARS, Consortium for Advanced Radiation Sources, The University of Chicago, Chicago, IL, U.S.A.;3James Franck Institute, The University of Chicago, Chicago, IL U.S.A. Introduction We have used X-ray Raman spectroscopy (XRS) to study the oxygen and carbon K-edges of high pressure phases of CO and CO2 to understand changes in chemical bonding associated with the pressure-induced molecular-to-nonmolecular phase transitions in these materials. This work has exploit the power of the XRS technique to resolve important scientific questions regarding the nature of the high-pressure phases of CO and CO2.
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