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Ligand intermediates in metal-catalyzed reactions; Annual technical report, August 1, 1992--August 1, 1993
Author(s) -
J.A. Gladysz
Publication year - 1993
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/144793
Subject(s) - ligand (biochemistry) , ketone , catalysis , aldehyde , transition metal , affinities , metal , chemistry , carbon fibers , carbon chain , chain (unit) , stereochemistry , polymer chemistry , medicinal chemistry , organic chemistry , materials science , physics , receptor , biochemistry , composite number , astronomy , composite material
Achievements are reported for the following 4 areas: {pi}/{sigma} equillibria in aldehyde and ketone complexes; thermodynamic ligand binding affinities ({alpha},{beta} unsaturated organic carbonyl compounds); (a new form of coordinated carbon) an unsupported C{sub 3} chain that spans two different transition metals; and (a new form of coordinated carbon) an C{sub 3} chain that is anchored by a metal on each end and spanned by a third

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