Phase equilibria modification by electric fields. 1997 annual progress report

'In this research program, Oak Ridge National Laboratory is investigating the modification of phase equilibria and interface transport enhancement-caused by electric fields. The majority of environmental and waste treatment processes involve complex chemical separations and reactions. The treatment efficiency in such processes is governed by thermodynamic equilibria and transport. The objective of this project is to use electric fields to favorably manipulate the thermodynamic and transport properties of mixtures so that higher separation efficiencies can be achieved. An understanding of the mechanisms of the underlying phenomena of molecular and fluid interactions with electric fields will lead to the development of efficient remediation methods for contaminated natural environments and wastes. Research Statement The main focus of this project is to understand and quantify the influence of electric fields on thermodynamic equilibria and transport properties of fluid mixtures and to determine the conditions and properties of the systems for which this influence is of practical significance. The specific objectives of the project are discussed.