Development of advanced electrochemical emission spectroscopy for monitoring corrosion in simulated DOE liquid waste. 1998 annual progress report
Author(s) -
D.D. Macdonald
Publication year - 1998
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/13462
Subject(s) - corrosion , carbon steel , electrochemistry , materials science , passivity , metallurgy , environmental science , engineering , chemistry , electrode , electrical engineering
'Objective of this project is to develop and use Electrochemical Emission Spectroscopy (EES) and other electrochemical techniques as in situ tools for exploring corrosion mechanisms of iron and carbon steel in highly alkaline solutions and for continuously monitoring corrosion on structural materials in DOE liquid waste storage system. In particular, the author will explore the fundamental aspects of the passive behavior of pure iron since breakdown of passivity leads to localized corrosion. This report summarizes work after 1 year of a 3 year project.
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