Comment on Temperature-Pressure Equilibrium Between Dispersed and Continuous Phases of a Material
Author(s) -
R.N. Lyon
Publication year - 1969
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/1062376
Subject(s) - sigma , saturation (graph theory) , thermodynamics , delta , physics , radius , phase (matter) , mathematics , combinatorics , quantum mechanics , computer security , astronomy , computer science
This memo calls attention to the fact that the relationship between equilibrium temperature and the pressures in two phases of a material is {Delta}sdT = {Delta}(vdP) , and not, as now routinely assumed by bubble investigators, the Clausius-Clapeyron equation {Delta}sdT = {Delta}vdP . If one phase is discontinuous (subscript "d") and consists of spheres of radius r in a continuous phase (subscript "c") whose pressure is held constant, then the equilibrium temperature will be above the saturation temperature of the continuous phase by an amount ({Delta}T{sub sup}){sub c} = 2 {integral}{sub 0}{sup ({sigma}/r){sub e}}(v{sub d}/{delta}s)d({sigma}/r) and above the saturation temperature of the discontinuous phase by an amount ({Delta}T{sub sup}){sub d} = 2 {integral}{sub 0}{sup ({sigma}/r){sub e}}(v{sub c}/{delta}s)d({sigma}/r
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