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Selective stress-based microcantilever sensors for enhanced surveillance.
Author(s) -
Mark D. Allendorf,
Aaron M. Katzenmeyer,
Vitalie Stavilla,
Joanne V. Volponi,
Louise Criscenti,
Jeffery A. Greathouse,
T.R. Guilinger,
N.W. Ockwig,
Phillip Isabio Pohl,
Alex Robinson,
Steven M. Thornberg,
Michael Irvin White,
Todd Zeitler,
Matthew C. Dixon,
JinHwan Lee,
Hakan Demir,
David S. Sholl,
Timothy Van Heest,
Ilya Ellern,
Peter J. Hesketh,
Anandram Venkatasubramanian
Publication year - 2012
Language(s) - English
Resource type - Reports
DOI - 10.2172/1057255
Subject(s) - cantilever , monolayer , molecular recognition , nanotechnology , surface stress , materials science , self assembled monolayer , selectivity , coating , biosensor , chemistry , molecule , organic chemistry , composite material , surface energy , catalysis
Assessment of component aging and degradation in weapon systems remains a considerable challenge for the Integrated Stockpile Evaluation program. Analysis of weapon atmospheres can provide degradation signatures and indicate the presence of corrosive vapors. However, a critical need exists for compatible in-situ sensors to detect moisture and other gases over stockpile lifetimes. This inhibits development of both “self-aware weapons” and fully instrumented weapon test platforms that could provide in-situ data to validate high-fidelity models for gases within weapons. We developed platforms for on-demand weapon atmosphere surveillance based on static microcantilevers (SMC) and surface accoustic wave (SAW) devices coated with nanoporous metal organic frameworks (MOFs) to provide selectivity. SMC detect analytes via adsorbate-induced stress and are up to 100X more sensitive than resonant

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