Adsorption performance of polydopamine-modified attapulgite granular adsorbent for methylene blue
Author(s) -
Weisheng Zheng,
Hailing Wang,
Zhaolian Zhu,
Peng Wei
Publication year - 2017
Publication title -
water science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.406
H-Index - 137
eISSN - 1996-9732
pISSN - 0273-1223
DOI - 10.2166/wst.2017.482
Subject(s) - adsorption , physisorption , methylene blue , endothermic process , langmuir adsorption model , fourier transform infrared spectroscopy , aqueous solution , chemical engineering , chemistry , nuclear chemistry , x ray photoelectron spectroscopy , desorption , scanning electron microscope , materials science , chromatography , organic chemistry , composite material , catalysis , photocatalysis , engineering
Polydopamine-modified granule organo-attapulgite adsorbent (PDA-GOAT) was facilely prepared via a dip-coating approach. The samples were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Surface area and pore size were calculated from the Brunauer-Emmett-Teller method by N 2 adsorption-desorption isotherm. The adsorption behaviour of methylene blue (MB) onto PDA-GOAT was systematically investigated. The experimental data revealed that the adsorption process fitted well with the pseudo-second-order kinetics equation and the adsorption isotherm fitted better with the Langmuir model. Thermodynamic analyses illustrated that MB adsorption onto PDA-GOAT was a physisorption endothermic process. Importantly, PDA-GOAT can be regenerated by NaBH 4 aqueous solution. The obtained results prove that PDA-GOAT can be a superior reusable adsorbent for the removal of MB from effluent.
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