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Synthesis and application of surface-modified NiFe nanoparticles as a new magnetic nano adsorbent for the removal of nickel ions from aqueous solution
Author(s) -
Yan Liu,
Xiaoyi Shen
Publication year - 2017
Publication title -
water science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.406
H-Index - 137
eISSN - 1996-9732
pISSN - 0273-1223
DOI - 10.2166/wst.2017.453
Subject(s) - adsorption , freundlich equation , aqueous solution , thermogravimetric analysis , fourier transform infrared spectroscopy , langmuir , nanoparticle , nickel , materials science , diffusion , chemical engineering , langmuir adsorption model , inorganic chemistry , chemistry , nuclear chemistry , organic chemistry , nanotechnology , metallurgy , thermodynamics , physics , engineering
Surface-modified magnetic Ni 2.33 Fe alloy nanoparticles were prepared using a hydrothermal method. Thermogravimetric analysis (TG) and Fourier transform infrared spectroscopy (FTIR) tests demonstrated that the surface was successfully modified by sodium citrate. The surface-modified particles can be used for removing nickel ions from aqueous solution. The adsorption kinetics studies were performed and the pseudo-second-order kinetic model successfully described the kinetic data. The diffusion model indicated the adsorption was regulated by both surface and intraparticle diffusion processes. The Freundlich and Langmuir adsorption models were adopted for the mathematical description of adsorption equilibrium, and it was found that the experimental data fitted very well to the Freundlich model.

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