Hen feather: a bio-waste material for adsorptive removal of methyl red dye from aqueous solutions
Author(s) -
Samina Zaman,
Md. Nayeem Mehrab,
Md Shahnul Islam,
Gopal Chandra Ghosh,
Tapos Kumar Chakraborty
Publication year - 2021
Publication title -
h2open journal
Language(s) - English
Resource type - Journals
ISSN - 2616-6518
DOI - 10.2166/h2oj.2021.123
Subject(s) - adsorption , aqueous solution , freundlich equation , fourier transform infrared spectroscopy , monolayer , chemistry , nuclear chemistry , langmuir adsorption model , langmuir , kinetics , diffusion , chromatography , analytical chemistry (journal) , chemical engineering , organic chemistry , biochemistry , engineering , quantum mechanics , physics , thermodynamics
This study investigates the potential applicability of hen feather (HF) to remove methyl red (MR) dye from aqueous solution with the variation of experimental conditions: contact time (1–180 min), pH (4–8), initial dye concentration (5–50 mg/L) and adsorbent dose (3–25 g/L). Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) evaluate the surface morphology and chemistry of HF, respectively. The maximum removal of MR by HF was 92% when the optimum conditions were initial MR dye concentration 5 mg/L, pH 4, adsorbent dose 7 g/L and 90 min equilibrium contact time. Langmuir isotherm (R2 = 0.98) was more suited than Freundlich isotherm (R2 = 0.96) for experimental data, and the highest monolayer adsorption capacity was 6.02 mg/g. The kinetics adsorption data fitted well to pseudo-second-order model (R2 = 0.999) and more than one process was involved during the adsorption mechanism but film diffusion was the potential rate-controlling step. The findings of the study show that HF is a very effective and low-cost adsorbent for removing MR dye from aqueous solutions.
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