Palladium(II) Complexes of Monodentate Phosphine Ligands and Their Application as Catalyst in Suzuki-Miyaura C-C Coupling Reaction at Room Temperature | Zendy

Mustafa Kemal Yılmaz | Zendy; Simay İnce | Zendy

Open Access

Palladium(II) Complexes of Monodentate Phosphine Ligands and Their Application as Catalyst in Suzuki-Miyaura C-C Coupling Reaction at Room Temperature

Author(s) -

Mustafa Kemal Yılmaz,

Simay İnce

Publication year - 2018

Publication title -

journal of the turkish chemical society section a chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.179

H-Index - 6

ISSN - 2149-0120

DOI - 10.18596/jotcsa.435122

Subject(s) - phenylboronic acid , palladium , bromobenzene , chemistry , phosphine , denticity , catalysis , aryl , steric effects , coupling reaction , solvent , polymer chemistry , medicinal chemistry , organic chemistry , crystal structure , alkyl

A series of palladium(II) complexes from monodentate phosphine ligands ( 1a-4a ) were successfully prepared and characterized with 1 H, 31 P, 13 C NMR, and HRMS techniques. These pre-catalysts were applied for the Suzuki -Miyaura C-C coupling reaction of phenylboronic acid with bromobenzene and the influence of the base and solvent on the performance of the pre-catalysts was investigated. Sterically hindered and electronically deactivated aryl bromides as well as activated ones gave the corresponding coupling products in good to excellent yields at room temperature.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research