Novel side reactions accompanying activation and aminolysis of N-benzoyl-2-alkylserines. | Zendy

Zbigniew J. Kamiñski | Zendy; A Woszczyna | Zendy; Beata Kolesińska | Zendy; Adam S. Redliński | Zendy

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Novel side reactions accompanying activation and aminolysis of N-benzoyl-2-alkylserines.

Author(s) -

Zbigniew J. Kamiñski,

A Woszczyna,

Beata Kolesińska,

Adam S. Redliński

Publication year - 2001

Publication title -

acta biochimica polonica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.452

H-Index - 78

eISSN - 1734-154X

pISSN - 0001-527X

DOI - 10.18388/abp.2001_3887

Subject(s) - aminolysis , chemistry , hydroxymethyl , yield (engineering) , oxazole , alkyl , amine gas treating , medicinal chemistry , side chain , stereochemistry , organic chemistry , catalysis , polymer , materials science , metallurgy

2-Phenyl-4-alkyl-4-hydroxymethyl-1,3-oxazolones (2a-d) have been identified as side products accompanying activation of N-benzoyl-2-alkylserines (1a-d). Oxazolones 2a-d in the presence of amine rearrange subsequently to corresponding 4-alkyl-2-phenyl-4,5-dihydro-1,3-oxazole-5 carboxylic acids (4a-d) at a 20-68% yield.

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