SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA | Zendy

Özgür Alver | Zendy; Cemal Parlak | Zendy

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SPECTROSCOPIC INVESTIGATIONS OF 1,4-DIOXANE ADSORBED ON BENTONITE FROM ANATOLIA

Author(s) -

Özgür Alver,

Cemal Parlak

Publication year - 2016

Publication title -

anadolu university journal of science and technology- a - applied sciences and engineering :

Language(s) - English

Resource type - Journals

ISSN - 2146-0205

DOI - 10.18038/btda.87236

Subject(s) - magic angle spinning , adsorption , bentonite , infrared , fourier transform infrared spectroscopy , solid state nuclear magnetic resonance , magic angle , infrared spectroscopy , hydrogen , chemistry , hydrogen bond , materials science , analytical chemistry (journal) , nuclear magnetic resonance , nuclear magnetic resonance spectroscopy , solid state , molecule , chemical engineering , organic chemistry , physics , optics , engineering

The adsorption of 1,4-dioxane on a natural bentonite sample from Unye region of Turkey has been examined using infrared and solid state magic angle spinning nuclear magnetic resonance spectroscopic techniques. It was observed that adsorption on bentonite is due to hydrogen bonding between the waters of interlayer and either hydrogen atoms of –CH 2 or oxygen atom of –CH 2 OCH 2 groups of 1,4-dioxane. No noticeable interactions, however, are observed at the Al-(Mg)-OH edges by FT-IR (Fourier Transform Infrared) and CP/MAS NMR (Cross Polarization/Magic Angle Spinning Nuclear Magnetic Resonance) techniques.

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