The peculiarities of the 4-carboxyphenylglyoxal and N-alkoxy-N’-arylureas interaction | Zendy

Vasiliy G. Shtamburg | Zendy; Victor V. Shtamburg | Zendy; Andrey A. Anishchenko | Zendy; Alexander V. Mazepa | Zendy

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The peculiarities of the 4-carboxyphenylglyoxal and N-alkoxy-N’-arylureas interaction

Author(s) -

Vasiliy G. Shtamburg,

Victor V. Shtamburg,

Andrey A. Anishchenko,

Alexander V. Mazepa

Publication year - 2020

Publication title -

european chemical bulletin

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.131

H-Index - 5

ISSN - 2063-5346

DOI - 10.17628/ecb.2020.9.339-344

Subject(s) - alkoxy group , moiety , substituent , diastereomer , aryl , alkyl , chemistry , medicinal chemistry , stereochemistry , organic chemistry

It was found that 3-alkoxy-4,5-dihydroxyimidazolidin-2-ones are the only products of interaction of N-alkoxyureas with arylglyoxals which have strong electronegative substituent in the forth position of the aryl moiety. The possibility of obtaining such products as 3-alkoxy-1aryl-5-(4-carboxyphenyl)-4,5-dihydroxyimidazolidin-2-ones, 3-alkoxy-1-alkyl-5-(4-carboxyphenyl)-4,5-dihydroxyimidazolidin-2-ones and 3-alkoxy-1-phenyl-4,5-dihydroxy-5-(4-nitrophenyl)-imidazolidin-2-ones has been verified in the experimental way. In most the cases 3alkoxy-4,5-dihydroxyimidazolidin-2-ones were produced as a mixture of diastereomers.

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