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The conversion of the 2(3 H )-furanone into the oxazinone and pyrimidinone derivatives is studied. A 2-(furan-3-ylmethylene)-4-oxo-4-phenylbutanoyl azide 3 was synthesized to carry out these conversions through its thermolysis in dry benzene and/or base-catalyzed decomposition of this azide in the presence of different amines. The structures of all compounds were demonstrated from their spectral data and elemental analyses.

ACCESS TO CONVENIENT SYNTHESIS OF OXAZINONE AND PYRIMIDINONE HETEROCYCLES DERIVED FROM 2(3H)-FURANONE