Synthesis, Characterization and Crystal Structure of Bis[1-methoxy-2,2,2-tris-(pyrazol-1-yl-κN2) ethane]-cobalt (II) bis-perchlorate | Zendy

Ganna Lyubartseva | Zendy; Sean Parkin | Zendy; Alex Nelson Davis | Zendy; U.P. Mallik | Zendy

Open Access

Synthesis, Characterization and Crystal Structure of Bis[1-methoxy-2,2,2-tris-(pyrazol-1-yl-κN2) ethane]-cobalt (II) bis-perchlorate

Author(s) -

Ganna Lyubartseva,

Sean Parkin,

Alex Nelson Davis,

U.P. Mallik

Publication year - 2020

Publication title -

journal of chemistry and biochemistry

Language(s) - English

Resource type - Journals

eISSN - 2374-2720

pISSN - 2374-2712

DOI - 10.15640/jcb.v8n1a1

Subject(s) - perchlorate , chemistry , triclinic crystal system , cobalt , acetonitrile , crystal structure , tris , pyrazole , ligand (biochemistry) , crystallography , medicinal chemistry , polymer chemistry , inorganic chemistry , organic chemistry , ion , biochemistry , receptor

Cobalt (II) perchlorate hexahydrate reacts with pyrazole based tripodal scorpionate ligand 1-methoxy-2,2,2tris(pyrazol-1-yl) ethane (1) in methanol, acetonitrile and water mixture as solvent to produce a new compound bis[1-methoxy-2,2,2-tris-(pyrazol-1-yl-κN2) ethane]-cobalt (II) bis-perchlorate (2). Pale yellow color block crystals suitable for single crystal X-ray diffraction study of the title complex were obtained by slow evaporation of the filtered reaction mixture in air. Title complex crystallizes in the triclinic space group P1 with unit cell parameters, a = 8.5762(1)Å, b =8.9617(1)Å, c = 11.6820(2) Å, α= 109.7814(7)o, β=93.1681(7)o and γ= 98.1972(7)o.

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