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Biodiesel Synthesis From Waste Cooking Oil Using CaO.SrO Catalyst By Transesterification Reaction In Batch Reactor
Author(s) -
Nuni Widiarti,
Ismi Arinal Haq,
F. Widhi Mahatmanti,
Harjito Harjito,
Cepi Kurniawan,
Surapto Suprapto,
Didik Prasetyoko
Publication year - 2018
Publication title -
jurnal bahan alam terbarukan
Language(s) - English
Resource type - Journals
eISSN - 2407-2370
pISSN - 2303-0623
DOI - 10.15294/jbat.v7i2.14925
Subject(s) - transesterification , catalysis , biodiesel production , calcination , biodiesel , methanol , crystallinity , batch reactor , coprecipitation , materials science , yield (engineering) , chemical engineering , chemistry , organic chemistry , metallurgy , composite material , engineering
CaO is a very good catalyst for oil transesterification reactions into biodiesel, but requires a reaction time of 2 hours to obtain equilibrium. The time of CaO catalysis reaction can be accelerated by modifying the CaO catalyst with SrO. Synthesis biodiesel of waste cooking oil has been successfully conducted by transesterification reaction that used batch reactor assisted by CaO.SrO catalyst. The aim of this study is to determine the characteristics and catalytic activity of catalyst in the transesterification reaction. Catalysts have been successfully synthesized by coprecipitation method with oil to methanol molar ratio of 1:1, and its calcined at 800 o C for 3 hours. Catalyst was characterized by XRD to determine the crystallinity. The smaller catalyst crystallinity obtained as the decline in intensity and shifts diffraction angles of CaO modified SrO catalyst. Surface area of catalyst characterized by SAA, that allow surface area between CaO modified SrO by 10.217 m 2 /g. Transesterification reaction performed on variation time (30, 60, 90, 120, 150 minutes), and the catalysts amount (1, 2, 4, 6, 8% w / v ). The optimum condition of catalytic activity in reaction for 2 hours and the catalyst amount is 1% w / v of reactants that produce yield of biodiesel is 96.4%.

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