PARAMETER INTERAKSI BINER KESETIMBANGAN UAP-CAIR CAMPURAN ALKOHOL UNTUK OPTIMASI PROSES PEMURNIAN BIOETANOL | Zendy

Asalil Mustain | Zendy; Anang Takwanto | Zendy; Dhoni Hartanto | Zendy

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PARAMETER INTERAKSI BINER KESETIMBANGAN UAP-CAIR CAMPURAN ALKOHOL UNTUK OPTIMASI PROSES PEMURNIAN BIOETANOL

Author(s) -

Asalil Mustain,

Anang Takwanto,

Dhoni Hartanto

Publication year - 2017

Publication title -

jurnal bahan alam terbarukan

Language(s) - English

Resource type - Journals

eISSN - 2407-2370

pISSN - 2303-0623

DOI - 10.15294/jbat.v4i2.5126

Subject(s) - uniquac , non random two liquid model , thermodynamics , binary number , activity coefficient , methanol , isobaric process , vapor–liquid equilibrium , root mean square , chemistry , materials science , mathematics , organic chemistry , physics , aqueous solution , arithmetic , quantum mechanics

In this work, the binary interaction parameters of vapor-liquid equilibrium for the mixtures of primary alcohols (methanol, ethanol, 1-propanol or 1-butanol) with C5 alcohols were obtained. A total of 15 systems that consisted of isobaric vapor-liquid equilibrium data at atmospheric pressure were selected. The binary interaction parameters were determined as temperature function by correlating the selected vapor-liquid equilibrium data using the Wilson, Non-Random Two-Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) activity coefficient models. The binary interaction parameters were described as the temperature-dependent to increase the capability of the parameters for the application in wide range of temperature. The correlation showed good results because the root mean square deviation (RMSD) between the calculation values and experimental data were relatively low. The obtained parameters were very useful for optimizing the distillation column in the bio-ethanol purification process. © 2016 Semarang State University Corresponding author: Jurusan Teknik Kimia, Politeknik Negeri Malang, Jl. Soekarno Hatta No. 9, Malang 65141 Indonesia E-mail: asalil89@polinema.ac.id ISSN 2303-0623

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