STARK AND ZEEMAN EFFECT STUDY OF THE [18.6]3.5 - X(1)4.5 BAND OF URANIUM MONOFLUORIDE, UF. | Zendy

C. Linton | Zendy; Timothy C. Steimle | Zendy; A. G. Adam | Zendy

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STARK AND ZEEMAN EFFECT STUDY OF THE [18.6]3.5 - X(1)4.5 BAND OF URANIUM MONOFLUORIDE, UF.

Author(s) -

C. Linton,

Timothy C. Steimle,

A. G. Adam

Publication year - 2014

Publication title -

proceedings of the 74th international symposium on molecular spectroscopy

Language(s) - English

Resource type - Conference proceedings

DOI - 10.15278/isms.2014.mg08

Subject(s) - zeeman effect , uranium , materials science , atomic physics , physics , nuclear physics , magnetic field , quantum mechanics

A high resolution spectrum of the [18.6]3.5 X(1)4.5 band of UF was obtained using the laser ablation specrometer at Arizona State University (ASU). The rotational structure showed significant perturbations in the upper state. Examination of the Stark and Zeeman splittings of the lowest J lines in electric fields up to 3.4 kV/cm and a magnetic field of 1650 Gauss yielded permanent electric dipole moments, μe, of 1.99 and 1.87 Debye and magnetic g-factors, ge of 3.28 and 3.26 for the ground and excited states respectively. The above experimental results will be discussed in terms of the configurational composition of the ground and excited states and compared with recent theoretical calculationsa.

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