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Dehydroamino acids are constitutents of certain peptide antibiotics and represent an important class of compound. Considerable attention has been given recently to the preparation of dehydroaminoacids, particularly of the dehydroalanine unit, which is generally derived from serine derivatives. In this study the conversion of a serine to a dehydroalanine unit using different base and solvents was investigated using N-benzyloxycarbonyl-O-tosyl derivative of serine.

ankara üniversitesi eczacılık fakültesi dergisi

INVESTIGATIONS ON THE EFFECT OF BASE AND SOLVENTS ON THE ELIMINATION OF p-TOLUENE SULPHONYL GROUP IN THE SYNTHESIS OF DEHYDRO ALANINE : p-TOLUEN SÜLFONİL GRUBU ELİMİNASYONU İLE DEHİDROALANİN SENTEZ