Synthesis of Propylene Carbonate over Metal containing Ionic Liquid Catalysts | Zendy

Yeji Moon | Zendy; Dahye Ji | Zendy; Dong-Woo Kim | Zendy; HyeonGook Kim | Zendy; Deug-Hee Cho | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Synthesis of Propylene Carbonate over Metal containing Ionic Liquid Catalysts

Author(s) -

Yeji Moon,

Dahye Ji,

Dong-Woo Kim,

HyeonGook Kim,

Deug-Hee Cho

Publication year - 2016

Publication title -

applied chemistry for engineering

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.144

H-Index - 11

eISSN - 2288-4505

pISSN - 1225-0112

DOI - 10.14478/ace.2015.1124

Subject(s) - ionic liquid , propylene carbonate , catalysis , propylene oxide , metal , chemistry , solvent , inorganic chemistry , ionic bonding , organic chemistry , ethylene oxide , electrolyte , polymer , ion , electrode , copolymer

In this study, three different metal-containing ionic liquid catalysts were prepared by metal insertion and characterized by various physicochemical analytic methods. The catalytic performance of the metal containing ionic liquids in the cycloaddition of CO2 with propylene oxide (PO) to produce propylene carbonate (PC) was investigated under the solvent free condition. The order of approximate rate constants (Kapp) for the metal containing ionic liquid catalysts was (MeIm)2ZnCl2, > (MeIm)2FeCl2 > (MeIm)2CuCl2. These results are in accord with the experimentally obtained activity order of the different metal containing ionic liquid catalysts.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research