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Enhancement of band-edge emission induced by defect transition in the composite of ZnO nanorods and CdSe/ZnS quantum dots
Author(s) -
Lin-Jie Tzeng,
Chung-Liang Cheng,
Yangfang Chen
Publication year - 2008
Publication title -
optics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.524
H-Index - 272
eISSN - 1071-2763
pISSN - 0146-9592
DOI - 10.1364/ol.33.000569
Subject(s) - nanorod , materials science , band gap , quantum dot , optoelectronics , excited state , semiconductor , wide bandgap semiconductor , nanocomposite , photoluminescence , excitation , optics , nanotechnology , atomic physics , physics , quantum mechanics
A new and general approach to enhance band-edge emission at the expense of defect emission in a semiconductor nanocomposite is proposed. The underlying mechanism is based on the resonance effect between defect transition and band-to-band excitation and transfer of excited electrons between conduction band edges. With our approach, it is possible to convert defect loss into bandgap emission. As an example, we demonstrate that the bandgap emission of ZnO nanorods can be enhanced by as much as 30 times when they are compounded with CdSe/ZnS nanoparticles.

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