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Intra-pulse laser absorption sensor with cavity enhancement for oxidation experiments in a rapid compression machine
Author(s) -
Ehson F. Nasir,
Aamir Farooq
Publication year - 2018
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.26.014601
Subject(s) - materials science , optics , laser , duty cycle , quantum cascade laser , absorption (acoustics) , spectroscopy , pulse compression , absorption spectroscopy , chirp , telecommunications , power (physics) , radar , physics , quantum mechanics , computer science , composite material
A sensor based on a mid-IR pulsed quantum cascade laser (QCL) and off-axis cavity enhanced absorption spectroscopy (OA-CEAS) has been developed for highly sensitive concentration measurements of carbon monoxide (CO) in a rapid compression machine. The duty cycle and the pulse repetition rate of the laser were optimized for increased tuning range, high chirp rate, and small line width to achieve effective laser-cavity coupling. This enabled spectrally resolved CO line-shape measurements at high pressures (P ~10 bar). A gain factor of 133 and a time resolution of 10 μs were demonstrated. CO concentration-time profiles during the oxidation of highly dilute n-octane/air mixtures were recorded, illustrating new opportunities in RCM experiments for chemical kinetics.

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