Optical properties of trivalent europium doped ZnO:Zn phosphor under indirect excitation of near-UV light
Author(s) -
Li Chen,
Jiahua Zhang,
Xianmin Zhang,
Feng Liu,
Xiaojun Wang
Publication year - 2008
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.16.011795
Subject(s) - phosphor , photoluminescence , europium , materials science , excitation , luminescence , doping , ion , photoluminescence excitation , energy transfer , analytical chemistry (journal) , zinc , optoelectronics , optics , chemistry , molecular physics , physics , organic chemistry , chromatography , quantum mechanics , metallurgy
Eu3+, Li+-codoped ZnO:Zn phosphor with intense Eu3+ emissions upon indirect excitation of near-UV light has been synthesized under reducing condition. Steady-state and time-resolved photoluminescence and diffuse reflectance spectra are measured to investigate properties of the luminescence. The results suggest that there exists prominent energy transfer from ZnO host to Eu3+ ions. A series of energy levels as temporary storage of excitation energy play a crucial role on this energy transfer process. Two kinds of Eu3+ sites in Eu3+, Li+-codoped ZnO:Zn are distinguished based on the emission and excitation spectra in comparison with pure Eu2O3.
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