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Well-dispersed quantum sized SnO2 nanoparticles have been successfully synthesized by simple solvothermal process using ethylenediamine as both a coordination and an alkali reagent. The size of the prepared tin oxide nanoparticle has been characterized by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) analysis. The TEM images show nano-particles as clusters with size in the range of 2.27–3.35 nm. Morphological studies were obtained by scanning electron microscopy (SEM). The optical direct band gap values of SnO2 nanoparticles were calculated to be about 3.75–4.27eV, which were confirmed the quantum size effect. The photoluminescence (PL) properties and the possible mechanisms were also discussed.

Solvents effect of quantum sized SnO2 nanoparticles via solvothermal process and optical properties