Acoustical Studies of Some Bio-Active Molecules in Aqueous 1,4-Dioxane Solutions At 298.15K
Author(s) -
V.K. PAGARE,
Sunil R. Mirgane,
A. R. Mahajan,
S. B. Deshmukh
Publication year - 2007
Publication title -
material science research india
Language(s) - English
Resource type - Journals
eISSN - 2394-0565
pISSN - 0973-3469
DOI - 10.13005/msri/040231
Subject(s) - aqueous solution , 1,4 dioxane , molecule , chemistry , combinatorial chemistry , computational chemistry , organic chemistry
The Density and Ultrasonic velocity measurement were carried out in aqueous solution of glycine, L-alanine, L-valine, L-Leucine and L-phenyl alanine in 10% 1,4-dioxane at 298.15 K Also from the density and ultrasonic velocity measurement, adiabatic compressibility (ad ) , intermolecular free length (Lf) specific acoustic impedance (z) Relative association (RA) and Hydration number (nH) are calculated at the temperatures, 298.15 K. All these parameters are related to type and extent of intermolecular interactions in binary liquid mixtures. All the results were interpreted in the light of ion -ion and ion – solvent interactions and of structural effect of solutes in solutions.
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