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"SEMICONDUCTING PROPERTIES OF CHARGE- TRANSFER COMPLEX OF NATURALLY OCCURRING COMPOUND “PROTOPINE"" WITH IODINE AND ITS APPLICATION IN SOLID - STATE BATTERIES"
Author(s) -
Ram Prakash Pandeya,
R. K. Guptab
Publication year - 2006
Publication title -
material science research india
Language(s) - English
Resource type - Journals
eISSN - 2394-0565
pISSN - 0973-3469
DOI - 10.13005/msri/030109
Subject(s) - protopine , solid state , iodine , materials science , charge (physics) , charge transfer complex , combinatorial chemistry , nanotechnology , chemistry , photochemistry , stereochemistry , physics , metallurgy , quantum mechanics , alkaloid
The chargetransfer (CT) complex based on protopine with electron acceptor iodine has been synthesized. The conductivity increases by several orders of magnitude and the activation energy decreases on formation of CT complex. Solidstate battery of configuration Zn protopineI2 / graphite has been developed using the CT complex as the cathodic material. The opencircuit voltage af the cell increases with the increase in temperature. The high opencircuit voltage and battery parameters indicate that the CT complex of natural occurring protopine can be used in fabrication of selidstate batteries.

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