Spectral, Magnetic and Thermal Studies of Some Chelate Polymers
Author(s) -
Harjeet D. Juneja,
Sachin Borkar
Publication year - 2004
Publication title -
material science research india
Language(s) - English
Resource type - Journals
eISSN - 2394-0565
pISSN - 0973-3469
DOI - 10.13005/msri/010206
Subject(s) - chelation , polymer , materials science , thermal , polymer science , polymer chemistry , thermodynamics , physics , metallurgy , composite material
The present paper describes the synthesis and structural features of some chelate polymers of Azeloyl bis p-tolyl carbamide (AZBPU) with first transition series metal ions viz. Mn(ll), Co(ll), Ni(|l) and Zn(ll). The resulting chelate polymers have been characterized on the basis of elemental analysis, electronics spectral and magnetic susceptibility studies. The nature of bonding has been discussed on the basis of IR spectral data. To ascertain there thermal stability a detailed thermal studies was carried out by Freeman-Carroll and Sharp-Wentworth methods
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