Application of Dispersive Liquid-Liquid Microextraction in Narrow-Bore Tube for Preconcentration and Spectrophotometric Determination of Cadmium in Aqueous Samples | Zendy

Mashaallah Rahmani | Zendy; Massoud Kaykhaii | Zendy; Malihe Harati No | Zendy

Open Access

Application of Dispersive Liquid-Liquid Microextraction in Narrow-Bore Tube for Preconcentration and Spectrophotometric Determination of Cadmium in Aqueous Samples

Author(s) -

Mashaallah Rahmani,

Massoud Kaykhaii,

Malihe Harati No

Publication year - 2016

Publication title -

eurasian journal of analytical chemistry

Language(s) - English

Resource type - Journals

ISSN - 1306-3057

DOI - 10.12973/ejac.2017.00163a

Subject(s) - chromatography , aqueous solution , cadmium , liquid liquid , tube (container) , chemistry , materials science , analytical chemistry (journal) , composite material , organic chemistry

A novel liquid phase microextraction based on narrow bore-dispersive liquid-liquid microextraction (NB-DLLME) is introduced and developed for preconcentration and extraction of cadmium in aquoeus samples using spectrophotometry. Unlike previous NBDLLME methods, in this research work a solvent with a density higher than water (carbon tetrachloride) is used as extractant solvent. The effects of different parameters such as kind and volume of extractant and dispersive solvent, internal diameter and lengnth of narrow bore, and concentration of salt are studied and optimized. Under optimum conditions, dynamic range of calibration curve was linear in the range of 50-900 μg.L. The detection limit and relative standard deveiation were calculated to be 6.3 μg.L and 6.4%, respectively.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research