Implications of treating water containing polynuclear aromatic hydrocarbons with chlorine: a gas chromatographic-mass spectrometric study.
Author(s) -
Alan R. Oyler,
Robert J. Liukkonen,
M K Lukasewycz,
Dean A. Cox,
David A. Peake,
Robert M. K. Carlson
Publication year - 1982
Publication title -
environmental health perspectives
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.257
H-Index - 282
eISSN - 1552-9924
pISSN - 0091-6765
DOI - 10.1289/ehp.824673
Subject(s) - phenanthrene , fluoranthene , chemistry , dibenzofuran , anthracene , fluorene , pyrene , chlorine , organic chemistry , phenols , naphthalene , acenaphthylene , chrysene , aqueous solution , gas chromatography , environmental chemistry , phenol , chromatography , polymer
The products of aqueous chlorination reactions of 1-methylnaphthalene, fluorene, dibenzofuran, anthracene, phenanthrene, 1-methylphenanthrene, fluoranthene, and pyrene have been determined. The conditions employed for these reactions approximated those that might be encountered in water treatment facilities. Reactions at pH greater than 6 tended to produce oxygenated products (epoxides, phenols, quinones, etc.), and reactions at pH less than 6 tended to produce both oxygenated (quinones) and chlorinated products.
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