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Instrumental aspects of positive and negative ion chemical ionization mass spectrometry.
Author(s) -
George C. Stafford
Publication year - 1980
Publication title -
environmental health perspectives
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.257
H-Index - 282
eISSN - 1552-9924
pISSN - 0091-6765
DOI - 10.1289/ehp.803685
Subject(s) - mass spectrometry , ion , chemistry , chemical ionization , mass spectrum , ionization , analytical chemistry (journal) , electron multiplier , quadrupole mass analyzer , electron ionization , detector , selected ion monitoring , physics , chromatography , optics , gas chromatography–mass spectrometry , organic chemistry
Differences in recording positive and negative ion chemical ionization mass spectra on a quadrupole mass spectrometer are discussed. An analog positive and negative ion electron multiplier detector is described which is well suited for a quadrupole instrument. This detector significantly reduces baseline noise in the negative ion mode and improves positive ion high mass sensitivity.

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