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A New Method of Synthesis of Alkyl β-Glycosides Using Sucrose as Sugar Donor
Author(s) -
Kuniki Kino,
Ryoko Satake,
Takayuki MORIMATSU,
Shoko Kuratsu,
Yu Shimizu,
Masaru Satô,
Kohtaro Kirimura
Publication year - 2008
Publication title -
bioscience biotechnology and biochemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.509
H-Index - 116
eISSN - 1347-6947
pISSN - 0916-8451
DOI - 10.1271/bbb.80097
Subject(s) - cellobiose , alkyl , chemistry , anomer , sucrose , glycogen phosphorylase , clostridium thermocellum , glucoside , hydrolysis , organic chemistry , glycoside , phosphorolysis , enzyme , cellulase , medicine , alternative medicine , purine nucleoside phosphorylase , pathology , purine
Cellobiose phosphorylase from Clostridium thermocellum catalyzed the beta-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl beta-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl beta-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.

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