Synthesis of Quinolactacideviaan Acyl Migration Reaction and Dehydrogenation with Manganese Dioxide, and Its Insecticidal Activities | Zendy

Masaki Abe | Zendy; Tetsuya Imai | Zendy; Naoki Ishii | Zendy; Makio Usui | Zendy

Open Access

Synthesis of Quinolactacideviaan Acyl Migration Reaction and Dehydrogenation with Manganese Dioxide, and Its Insecticidal Activities

Author(s) -

Masaki Abe,

Tetsuya Imai,

Naoki Ishii,

Makio Usui

Publication year - 2006

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.70.303

Subject(s) - plutella , diamondback moth , dehydrogenation , myzus persicae , manganese , aphid , chemistry , organic chemistry , penicillium citrinum , horticulture , medicinal chemistry , botany , biology , catalysis , food science , lepidoptera genitalia

Quinolactacide isolated from Penicillium citrinum F 1539 was synthesized and evaluated for its insecticidal activities. The key steps of the total synthesis were an acyl migration reaction of the enol ester intermediate and dehydrogenation of tetrahydroquinolactacide with manganese dioxide. The synthesized quinolactacide showed 100% and 42% mortality against the green peach aphid (Myzus persicae) and diamondback moth (Plutella xylostella) at 500 ppm, respectively.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research