Oligomerization ofN-Tosylindole with Aluminum Chloride
Author(s) -
Kazutaka Fujino,
Emiko Yanase,
Yoshihiko Shinoda,
Shinichi Nakatsuka
Publication year - 2004
Publication title -
bioscience biotechnology and biochemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.509
H-Index - 116
eISSN - 1347-6947
pISSN - 0916-8451
DOI - 10.1271/bbb.68.764
Subject(s) - trimer , pyrrole , chloride , benzene , condensation , chemistry , reactivity (psychology) , indole test , aluminium , nucleus , polymer chemistry , dimer , medicinal chemistry , stereochemistry , organic chemistry , physics , medicine , alternative medicine , pathology , thermodynamics , microbiology and biotechnology , biology
The reactivity of N-tosylindole (4) in the presence of aluminum chloride was studied, and two types of oligomerization of 4 were observed. One type was condensation between both pyrrole parts (dimers 5 and 6 and trimer 7) and the other was between a pyrrole part and a benzene part of each indole nucleus (dimers 8 and 9).
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