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In our search for new cyathane metabolites related to the biosynthesis of erinacine Q in Hericium erinaceum, we isolated a novel cyatha-3,12-dien-14beta-ol named erinacol together with known 11-O-acetylcyathatriol (the erinacine Q aglycon) and new metabolite 11-O-acetylcyathin A(3) from the mycelial extract. The structure of each compound was determined by spectral methods. Possible biosynthetic relationships of these metabolites are discussed from their structural features.

bioscience, biotechnology, and biochemistry

Erinacol (Cyatha-3,12-dien-14β-ol) and 11-O-Acetylcyathin A3, New Cyathane Metabolites from an Erinacine Q-ProducingHericium erinaceum