New Method for Synthesizing the Intermediates to 5-HETE from Yeast-mediated Reduction Products by Employing Baeyer-Villiger Oxidation with Complete Retention of Enantiomeric Excess | Zendy

Satoshi Yamauchi | Zendy; Yoshihiro Kinoshita | Zendy; Yoshiro Kinoshita | Zendy

Open Access

New Method for Synthesizing the Intermediates to 5-HETE from Yeast-mediated Reduction Products by Employing Baeyer-Villiger Oxidation with Complete Retention of Enantiomeric Excess

Author(s) -

Satoshi Yamauchi,

Yoshihiro Kinoshita,

Yoshiro Kinoshita

Publication year - 2003

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.67.1959

Subject(s) - chemistry , yeast , enantiomer , enantiomeric excess , baeyer–villiger oxidation , lactone , stereochemistry , walden inversion , organic chemistry , enantioselective synthesis , catalysis , biochemistry

(R) and (S)-Aldehydes 2, which are intermediates for the synthesis of (5R) and (5S)-HETE, were respectively synthesized from the yeast-mediated reductive products, hydroxy ester 3 and cis-lactone 4, through Baeyer-Villiger oxidation with complete retention of enantiomeric excess.

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