Synthesis of the Racemate of (Z)-exo-α-Bergamotenal, a Pheromone Component of the White-spotted Spined Bug,Eysarcoris parvusUhler | Zendy

Hossein Heidary | Zendy; Shigefumi Kuwahara | Zendy; Walter Soares Leal | Zendy; Hong-Chao MEN | Zendy

Open Access

Synthesis of the Racemate of (Z)-exo-α-Bergamotenal, a Pheromone Component of the White-spotted Spined Bug,Eysarcoris parvusUhler

Author(s) -

Hossein Heidary,

Shigefumi Kuwahara,

Walter Soares Leal,

Hong-Chao MEN

Publication year - 2002

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.66.1415

Subject(s) - regioselectivity , wittig reaction , pheromone , stereochemistry , component (thermodynamics) , sequence (biology) , sex pheromone , chemistry , biology , organic chemistry , physics , botany , catalysis , biochemistry , thermodynamics

The racemate of (Z)-exo-alpha-bergamotenal, a sex pheromone component of the white-spotted spined bug, was synthesized from racemic exo-alpha-bergamotene by a five-step sequence involving regioselective epoxidation and (Z)-selective Wittig olefination reactions. The 1H- and 13C-NMR spectra of the synthetic sample were identical with those of the natural material.

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