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The asymmetric biohydrolysis is described of o-nitrostyrene oxide with high selectivity by whole cells of Aspergillus niger CGMCC 0496. Both the epoxide and diol could be obtained in a high state of optical purity (over 98%). Product inhibition was found when using a high ratio of substrate to cells.

Enantioselective Hydrolysis ofo-Nitrostyrene Oxide by Whole Cells ofAspergillus nigerCGMCC 0496