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Syntheses of (±)-Methyl 6′α-Demethyl-6′α-cyanoabscisate and (±)-Methyl 6′α-Demethyl-6′α-methoxycarbonylabscisate
Author(s) -
Takahiro Inoue,
Takayuki Oritani
Publication year - 2000
Publication title -
bioscience biotechnology and biochemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.509
H-Index - 116
eISSN - 1347-6947
pISSN - 0916-8451
DOI - 10.1271/bbb.64.1071
Subject(s) - regioselectivity , hydrocyanation , abscisic acid , chemistry , elongation , stereochemistry , methyl group , organic chemistry , group (periodic table) , biochemistry , materials science , catalysis , gene , ultimate tensile strength , metallurgy
New abscisic acid analogs possessing a cyano or methoxycarbonyl group at the 6'alpha-position of methyl abscisate were synthesized by regioselective hydrocyanation. These compounds had weak activity in the rice second leaf sheath elongation test.

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