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Water Sorption and Drying Behavior of Crosslinked Dextrans
Author(s) -
Masatoshi Ruike,
Tomohiro Inoue,
Shingo Takada,
Kyoji Horie,
Norio Murase
Publication year - 1999
Publication title -
bioscience biotechnology and biochemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.509
H-Index - 116
eISSN - 1347-6947
pISSN - 0916-8451
DOI - 10.1271/bbb.63.271
Subject(s) - sorption , desorption , hysteresis , chemical engineering , polymer , materials science , polymer chemistry , chromatography , chemistry , adsorption , organic chemistry , composite material , physics , quantum mechanics , engineering
The water sorption and drying behavior of crosslinked dextran gels was investigated in relation to the dependency on the density of the crosslinks. Sorption isotherms indicate that the amount of sorption was more for the gels with a lower crosslink density. Almost all the isotherms show sorption and desorption hysteresis, the extent of this hysteresis being more marked with the gels with lower crosslink density. The rate of drying was also dependent on the crosslink density. These results can be explained by considering that the polymer network in a gel with a low crosslink density is more flexible to easy change during water sorption and drying than in one with a higher crosslink density.

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