Positional Isomers of Monohydroperoxides Produced by Peroxidation of Phosphatidylcholine Containing an Arachidonoyl Moiety in a Liposomal Suspension | Zendy

Hidetaka Kobayashi | Zendy; Akihiko Nagao | Zendy; Junji Terao | Zendy

Open Access

Positional Isomers of Monohydroperoxides Produced by Peroxidation of Phosphatidylcholine Containing an Arachidonoyl Moiety in a Liposomal Suspension

Author(s) -

Hidetaka Kobayashi,

Akihiko Nagao,

Junji Terao

Publication year - 1999

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.63.1308

Subject(s) - phosphatidylcholine , moiety , liposome , chemistry , lipid peroxidation , suspension (topology) , stereochemistry , organic chemistry , biochemistry , antioxidant , phospholipid , membrane , pure mathematics , mathematics , homotopy

Monohydroperoxides derived from the peroxidation of 1-palmitoyl-2-arachidonoyl-phosphatidylcholine (PC-AA) in a liposomal suspension had a characteristic isomeric composition. Of the two possible isomers derived from a pentadienyl-radical intermediate, the isomer with a hydroperoxy group on the carboxyl-terminal side was at a substantially lower level than the other.

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