Autoxidation Reaction Mechanism forL-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis | Zendy

Noriko Miyake | Zendy; Tadao KURATA | Zendy

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Autoxidation Reaction Mechanism forL-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis

Author(s) -

Noriko Miyake,

Tadao KURATA

Publication year - 1998

Publication title -

bioscience biotechnology and biochemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.509

H-Index - 116

eISSN - 1347-6947

pISSN - 0916-8451

DOI - 10.1271/bbb.62.811

Subject(s) - autoxidation , chemistry , ascorbic acid , catalysis , methanol , metal , adduct , reaction mechanism , oxygen , organic chemistry , medicinal chemistry , combinatorial chemistry , food science

The autoxidation mechanism for L-ascorbic acid (ASA)-related compounds such as D-arabo-ascorbic acid (=erythorbic acid; ERA) and triose reductone (TR) in methanol without metal ion catalysis was studied. The oxidation reaction of these ASA-related compounds seems to proceed via the C(2) oxygen adduct of ERA (or TR) by a similar reaction mechanism to that of ASA.

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